Saturday, November 30, 2013

A comparison between the Enthalpy of formation of MgO acquired via a series of reactions and Hess's Law (will they be equivalent?)

Enthalpy of FormationBackgroundThe total disturb of system (ΔH°f) is specify as the rouse change associated with the make-up of one groin of a commingle from its elements in their standard states. The major barricade here, though, is that it is very unvoiced to measure most enthalpies of formations in a standard lab due to the amount of heat or toxic products that argon formed. Thus, in invest to acquire the in demand(p) results, one essential use Hess?s Law in which the hydrogen of a series of reactions are measured and added unneurotic to pass the utmost answer of the enthalpy of formation. In this situation, to mould the enthalpy of formation for MgO is very difficult in the lab (Mg(s) + ½ O2 (g) MgO(s)). But, by means of a series of reactions and Hess?s Law, the determination of the enthalpy of formation is make possible. Thus, in this investigation, we leave see how hi-fi and precise Hess?s Law can be. MgO(s) + 2 H+(aq) Mg2+(aq) + H2O(l) Δ ;H°2 = ?Mg(s) + 2 H+(aq) Mg2+(aq) + H2(g) ΔH°3 = ?+H2(g) + ½ O2(g) H2O(l) ΔH°4 = ?286 kJ/molMg(s) + ½ O2 (g) MgO(s) ΔH°f = ?The series of reactions that will be use and whose enthalpies will be combined to give the enthalpy of formation of MgO are listed above. The offset shade, though, has MgO in the reactant identify outment, but in the equality above that, MgO is supposed to be in the product side (enthalpy of formation). Thus, the sign for the enthalpy of the first reaction must be switched; if it?s positive, then it becomes contradict and vice versa. Hypothesis:If a series of reactions are utilise to determine the ΔH°f of MgO, then the experimental shelter acquired in this investigation should be very close to the accept value due to Hess?s Law. Variables:Independent Variables:The Molarity of the acidulent usedThe type and amount of the elements usedDependent Variables:The enthalpy of formation of the MgOControl of Variables:Several r eactions that get to been careful construct! ed are performed to a lower place additional conditions to acquire the desired results. Materials and MethodMaterials200ml of 3.
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0M HClGraduated CylinderMagnesium StripsThermometerStyrofoam Cup w/LidWeighing ScaleMgO powderMethod and Procedure component 1: MgO(s) + 2 H+(aq) Mg2+(aq) + H2O(l)1.Take the Styrofoam loving cup and put 100 ml of 3.0 M HCl in it. 2.Weigh out about one thou of close-grained MgO. 3.Make a very small hole in the hat of the Styrofoam cup just big enough for the thermometer to fill through so no heat escapes. 4.Record the initial temperature of the HCl5.Then, place the MgO into the cup and q uickly place the lid on it to counteract the heat from escaping6.Pick up the cup and stir it and record the largest temperature reached by the reaction. break off 2: Mg(s) + 2 H+(aq) Mg2+(aq) + H2(g)1.Repeat every step from Part 1 except use about 0.5 g of Mg metal (strips) instead of the MgO and record the initial and lowest temperatures in the cup. If you want to get a full essay, order it on our website: BestEssayCheap.com

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